Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 63, Pages 8838-8841Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc04382a
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Kanazawa University SAKIGAKE Project
- Grants-in-Aid for Scientific Research [16K05850, 17H01200] Funding Source: KAKEN
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A (mu-peroxo)diiron(III) complex [Fe-2(L-Ph4)(O-2)(Ph3CCO2)](2+) (1-O-2) with a dinucleating ligand (L-Ph4), generated from the reaction of a carboxylate bridged diiron(II) complex [Fe-2(L-Ph4)(Ph3CCO2)](2+) (1) with dioxygen in CH2Cl2, provides a diiron(IV)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation.
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