Journal
ELECTROCHIMICA ACTA
Volume 246, Issue -, Pages 406-414Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2017.06.067
Keywords
Anion exchange; Pillar effect; Layered double hydroxide; Surfactant; Supercapacitor
Categories
Funding
- National Natural Science Foundation of China [41572034, 51462007]
- Guangxi Natural Science Foundation [2014GXNSFAA118349, 2015GXNSFCA139018, 2015GXNSFFA139003]
- Guilin University of Technology and Guangxi Universities Key Laboratory of Non-Ferrous Metal Oxide Electronic Functional Materials and Devices
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In terms of the charge storage mechanism of supercapacitors, there are three types, including electrical double layer (EDL), surface redox reaction and intercalation reaction. The surface redox mechanism of transition metal-layered double hydroxides (TM-LDH) supercapacitor had been previously revealed. A dual charge storage mechanism integrated with surface redox and ion intercalation for LDH-based supercapacitors, however, is seldom reported before. For this purpose, here, we synthesized NiCo layered double hydroxide nanosheets via the intrinsic pillar effect of sodium dodecylbenzene sulfonate (NiCoSDBS-LDH), and found that the surface redox and intercalation behaviors take effect simultaneously in NiCo-SDBS-LDH via electrochemical analysis. The NiCo-SDBS-LDH electrode having a relatively low specific surface area (15.28m(2) g (1)) still exhibited a remarkable specific capacitance of 1094 F g (1) at a scan rate of 5 A g (1), and super long cycle life of 81% retention over 3000 cycles. A dual charge storage mechanism is subsequently proposed based on the analysis of our results to explain the excellent properties of NiCo-SDBS-LDH. We believe that the enhancements should mainly be ascribed to the structural feature of the SDBS stabilized NiCo-LDH and the expanded interlayer space of NiCo-SDBS-LDH. These findings open new doors to functional pillared effect to control the electrochemical behaviors of TM-LDH-based materials. (C) 2017 Elsevier Ltd. All rights reserved.
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