Journal
CRYSTENGCOMM
Volume 19, Issue 29, Pages 4142-4146Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ce02621d
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Funding
- CONACyT, Mexico [236879]
- UNAM, Mexico [PAPIIT IA201117]
- CONACyT Mexico [212318]
- PAPIIT UNAM Mexico [IN100415, IN101517]
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Crystalline Cu(II)-MOP 1 was employed for the first time in the catalytic conversion of trans-ferulic acid to vanillin. The generation of uncoordinated Cu(II) metal sites within MOP 1 by activation as well as sonication, revealed its catalytic potential that afforded a reaction yield of 60%. Complementary cyclic voltammetry experiments (CVs) demonstrated the formation of the complex Cu-H2O2, which supported the reaction mechanism proposed here.
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