Journal
CRYSTENGCOMM
Volume 19, Issue 29, Pages 4152-4156Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ce00094d
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Funding
- Research Foundation - Flanders (FWO)
- KU Leuven
- MATsynCELL project through the RontgenAngstrom Cluster
- Swedish Research Council
- German Federal Ministry of Education and Research (BMBF)
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We report the water-induced transformation of the [Zn-2(dobdc)] (dobdc = 2,5-dioxidobenzene-1,4-dicarboxylate) metal-organic framework UTSA-74 to its polymorph MOF-74.Zn), contrary to a previous report on the stability of UTSA-74 under such conditions. This dissolution-recrystallization process was investigated using time-resolved in situ X-ray diffraction and kinetically analyzed using the Gualtieri crystallization model.
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