4.7 Article

Tracking the FeIV(O) intermediate and O-O bond formation of a nonheme iron catalyst for water oxidation

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 65, Pages 9063-9066

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc04814a

Keywords

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Funding

  1. Ministry of Science and Technology of China [2014CB239402, 2013CB834505, 2013CB834804]
  2. National Science Foundation of China [91427303, 21390404, 51373193]
  3. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB17030300]
  4. Chinese Academy of Sciences

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To identify the short-lived, highly-active iron intermediate generated in situ for water oxidation, we describe here a new complex 1 by subtle modulation of the TPA ligand and succeed in capturing the high-valent Fe-IV(O) species, which is responsible for the O-O bond formation and oxygen evolution with higher efficiency.

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