Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 33, Pages 9837-9841Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201705007
Keywords
corroles; gold; photophysics; proton reduction; trifluoromethylation
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Funding
- Pazy Foundation
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Gold corroles are not readily accessible and they display no interesting physical or chemical properties. A facile methodology has now been developed for obtaining selectively CF3-substituted gold(III) corroles and the introduction of these groups has been found to have an immense effect on the structures of the complexes, their photophysical and redox properties, and on their ability to participate in catalytic processes.
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