Journal
CHEMICAL RECORD
Volume 17, Issue 8, Pages 754-774Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201600125
Keywords
visible light; photoredox; C-H functionalization; radical; photochemistry
Categories
Funding
- National Natural Science Foundation of China [21472084, 21672098]
Ask authors/readers for more resources
Visible-light photoredox catalysis has been successfully used in the functionalization of inert C-H bonds including C(sp(2))-H bonds of arenes and C(sp(3))-H bonds of aliphatic compounds over the past decade. These transformations are typically promoted by the process of single-electron-transfer (SET) between substrates and photo-excited photocatalyst upon visible light irradiation (household bulbs or LEDs). Compared with other synthetic strategies, such as the transition-metal catalysis and traditional radical reactions, visible-light photoredox approach has distinct advantages in terms of operational simplicity and practicability. Versatile direct functionalization of inert C(sp(2))-H and C(sp(3))-H bonds including alkylation, trifluoromethylation, arylation and amidation, has been achieved using this practical strategy.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available