Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 36, Pages 10915-10919Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201706263
Keywords
iridium; photochemistry; radicals; reaction mechanisms; synthetic methods
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Funding
- ICIQ
- European Research Council [ERC-277883]
- MINECO (Severo Ochoa Excellence Accreditation) [SEV-2013-0319, CTQ2015-65496-R]
- Cellex Foundation
- COFUND
- CSC
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A redox-neutral intermolecular dicarbofunctionalization of styrenes with CO2 at atmospheric pressure and carbon-centered radicals is described. This mild protocol results in multiple C-C bond-forming reactions from simple precursors in the absence of stoichiometric reductants, thus exploiting a previously unrecognized opportunity that complements existing catalytic carboxylation events.
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