Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 36, Pages 10877-10880Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201704385
Keywords
alkenes; nitrogen heterocycles; photochemistry; radicals; reaction mechanisms
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Funding
- Hundred Talent Program of Chinese Academy of Sciences
- National Natural Science Foundation of China [21602229]
- State Key Laboratory for Oxo Synthesis and Selective Oxidation
- Lanzhou Institute of Chemical Physics
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A simple and practical visible-light-induced carbo-2-pyridylation of electron-deficient alkenes with readily available N-benzoylmethylpyridinium bromides is reported. More than 40 examples are presented and proceed in greater than 80% yield (on average) with excellent regio- and diastereoselectivities.
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