4.8 Article

Dentritic CuPtPd Catalyst for Enhanced Electrochemical Oxidation of Methanol

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 9, Issue 31, Pages 25995-26000

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b06296

Keywords

enhanced electrocatalysis; antipoisoning; dendritic; ternary; methanol

Funding

  1. National Natural Science Foundation of China [21475088]
  2. International Joint Laboratory on Resource Chemistry (IJLRC)
  3. Shanghai Key Laboratory of Rare Earth Functional Materials
  4. Shanghai Municipal Education Committee Key Laboratory of Molecular Imaging Probes and Sensors

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The CuPtPd catalyst is designed and synthesized successfully via directly reducing metal ions. The composition, morphology, and structure of the as-prepared CuPtPd nanohybrids are characterized by scanning electron microscopy and transmission electron microscopy, energy-dispersive spectrometry, selected-area electron diffraction, X-ray diffraction, and inductively coupled plasma atomic emission spectrometry. By comparison of the electrocatalytic properties of the ternary CuPtPd catalyst with bimetallic catalysts, we find that ternary nanocomposites perform better electrocatalytic and antipoisoning activity toward oxidation of methanol. The catalytic mass activity of the CuPtPd nanoparticles is 5.51-fold of commercial Pd black and 12.1-fold of Pt black.

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