4.6 Article

Underscreening, overscreening and double-layer capacitance

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 82, Issue -, Pages 129-133

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2017.07.008

Keywords

Concentrated electrolytes; Room temperature ionic liquids; Debye length; Mean-field; Underscreening; Overscreening

Funding

  1. Alexander von Humboldt Foundation
  2. Thomas Young Centre (UK)
  3. Engineering and Physical Sciences Research Council [EP/H004319/1] Funding Source: researchfish
  4. EPSRC [EP/H004319/1] Funding Source: UKRI

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There have recently been reports of extraordinarily long screening lengths in concentrated electrolytes and which vary non-monotonically with ion concentration. There were several attempts to explain these puzzling observations. In this communication we further explore possibilities to rationalise those results. Our analysis does not yet close the problem, but it highlights conflicting consequences of the models designed to reproduce those observations.

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