Journal
CHEMICAL RECORD
Volume 17, Issue 9, Pages 833-840Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201600129
Keywords
asymmetry; hydrophosphonylation; -hydroxy phosphonates; organocatalysis; phosphite; Pudovik
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Funding
- Spanish High Research Council (CSIC) [PIE-201580I010]
- Gobierno de Aragon-Fondo Social Europeo [E104]
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This revision is covering the limited examples reported for a pivotal strategy in the formation of C-P bonds such as the asymmetric organocatalytic hydrophosphonylation of carbonyl groups (Pudovik reaction). The scope and limitations, and the proposed mechanisms for the scarce different possibilities of asymmetric induction are also shown. The recent evolution and future trends of this undeveloped approach are commented.
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