Journal
CATALYSIS COMMUNICATIONS
Volume 100, Issue -, Pages 112-116Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2017.06.034
Keywords
NH3-SCR; Ca poisoning; Regeneration; Mechanism; Coordination interaction
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Funding
- National Natural Science Foundation of China [21325731, 51478241]
- Public Projects Foundation of China, Ministry of Environmental Protection [201509021, 201509012]
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Polyether surfactant was employed for the regeneration of a poisoned by calcium V2O5-WO3/TiO2 catalyst. The OP-10 (alkylphenol polyoxyethylene (10) ether) surfactant exhibited better CaO removal performance than EL-60 (cremophor EL 60) and AEO9 (polyethyleneglycol (9) mono-dodecyl ether). The Ca2+-aromatic interactions developed in OP-10 increased the solubility of CaO in water and Ca2+ could be removed by washing. The high Ca2+ removal rate by OP-10 surfactant led to the reversible improvement of surface acid sites and active oxygen species. Compared with the traditional method of dilute sulfuric acid solution, the OP-10 presented higher Ca2+ removal rate with lower V2O5 loss, which is expected to be a facile and environmental benign method for the regeneration of Ca2+-poisoned NH3-SCR industrial catalysts.
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