Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 359, Issue 17, Pages 3063-3067Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700423
Keywords
fluorine; photocatalysis; silyl enol ethers; radical reactions; fluoroalkylation
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Funding
- Ministry of Science [MK-6724.2016.3]
- Russian Foundation for Basic Research [16-29-10661]
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A method for the synthesis of beta, beta-difluorinated ketones by coupling of alpha, alpha-difluorinated iodides with silyl enol ethers is described. The reaction is performed in the presence of iridium(III) photocatalysts under the irradiation with 400 nm light emitting diodes.
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