Journal
CRYSTENGCOMM
Volume 19, Issue 33, Pages 4868-4871Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ce00593h
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Funding
- Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DESC0001015]
- U.S. Department of Energy, Office of Fossil Energy, National Energy Technology Laboratory [DE-FE0026472]
- Welch Endowed Chair [A-0030]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
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The design and synthesis of flexible monomer-based covalent organic frameworks (COFs) have been considered a challenge. Herein, we describe the design and synthesis of a new flexible monomer-based COF, termed PPN-30 (PPN meaning porous polymer network), by the use of a flexible alkyl amine, 1,4-cyclohexanediamine, combined with 1,3,5-triformylbenzene. The structure and gas adsorption properties of PPN-30 were carefully investigated.
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