4.7 Article

Naphthol synthesis: annulation of nitrones with alkynes via rhodium(III)-catalyzed C-H activation

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 69, Pages 9640-9643

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05000c

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Funding

  1. National Natural Science Foundation of China [21525208, 21472186]

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An efficient and redox-neutral naphthol synthesis has been realized via rhodium(III) catalyzed C-H activation of alpha-carbonyl nitrones and annulation with alkynes, where the nitrone group functioned as a traceless directing group.

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