Journal
CHEMICAL SCIENCE
Volume 8, Issue 1, Pages 734-741Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc02832b
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Funding
- National Research Foundation of Korea (NRF) - Korean Government (MSIP) [2009-0081571[RIAM0417-20150013]]
- Global Frontier R&D Program at the Center for Multiscale Energy Systems - National Research Foundation under the Ministry of Science, ICT & Future Planning, Korea [2012M3A6A7055540, NRF-2015M1A2A2056542]
- Korea Research Institute of Chemical Technology (KRICT), Republic of Korea [KK1602-A01]
- Basic Science Research Program through the NRF - Ministry of Education [NRF-2015R1A6A3A04058164]
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We have designed and synthesized fluorinated indolo[3,2-b] indole (IDID) derivatives as crystalline holetransporting materials (HTM) for perovskite solar cells. The fluorinated IDID backbone enables a tight molecular arrangement stacked by strong pi-pi interactions, leading to a higher hole mobility than that of the current HTM standard, p, p-spiro-OMeTAD, with a spherical shape and amorphous morphology. Moreover, the photoluminescence quenching in a perovskite/HTM film is more effective at the interface of the perovskite with IDIDF as compared to that of p, p-spiro-OMeTAD. As a consequence, the device fabricated using IDIDF shows superior photovoltaic properties compared to that using p, p-spiroOMeTAD, exhibiting an optimal performance of 19%. Thus, this remarkable result demonstrates IDID core-based materials as a new class of HTMs for highly efficient perovskite solar cells.
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