Journal
CHEMICAL SCIENCE
Volume 8, Issue 2, Pages 1344-1349Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc04006c
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Funding
- European Union [623605]
- University of Basel
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The first efficient palladium(0)-catalyzed enantioselective C(sp3)-H activation reaction using a catalytic chiral base and an achiral phosphine ligand is reported. Fine-tuning the binol-derived phosphoric acid pre-catalyst and the reaction conditions was found to be crucial to achieve high levels of enantioselectivity for a variety of indoline products containing both tri-and tetrasubstituted stereocenters.
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