Journal
CHEMICAL SCIENCE
Volume 8, Issue 4, Pages 2610-2615Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc05093j
Keywords
-
Categories
Funding
- Natural Science Foundation of China
- Shandong province [21572118, JQ201505]
- fundamental research and subject construction funds [2014JC008, 104.205.2.5]
- Shandong University
Ask authors/readers for more resources
Regioselective difunctionalization of alkenes has attracted significant attention from synthetic chemists and has the advantage of introducing diverse functional groups into vicinal carbons of common alkene moieties in a single operation. Herein, we report an unprecedented intermolecular atom transfer thiosulfonylation reaction of alkenes by combining gold catalysis and visible-light photoredox catalysis. A trifluoromethylthio group (SCF3) and other functionalized thio groups together with a sulfonyl group were regioselectively introduced into alkenes in the most atom economical manner. A detailed mechanism study indicated that a synergistic combination of gold catalysis and photoredox catalysis is crucial for this reaction.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available