Journal
CHEMICAL SCIENCE
Volume 8, Issue 2, Pages 946-952Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc03699f
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Funding
- European Research Council [ERC-2011-StG-277801]
- Spanish MINECO [CTQ2013-43012-P, CTQ2015-64436-P, Consolider-Ingenio CSD2010-00065, INP-2011-0059-PCT-420000-ACT1]
- Generalitat de Catalunya [SGR 862]
- UdG
- ICREA-Academia award
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Au(III)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C-O and C-N cross coupling catalysis. The crystal structures of cyclometalated neutral and cationic Au(III) species are described and their key role in 2 electron-redox Au(I)/Au(III) catalysis in C-O and C-N cross couplings is shown. Nucleophiles compatible with Au-catalyzed cross couplings include aromatic and aliphatic alcohols and amines, as well as water and amides.
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