Journal
CHEMICAL SCIENCE
Volume 8, Issue 2, Pages 1056-1061Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc03471c
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Funding
- Swedish Research Council (VR)
- Knut och Alice Wallenbergs Foundation
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A new method is presented for 1,3-difluorination and 1,3-oxyfluorination reactions. The process is based on iodonium mediated opening of 1,1-disubstituted cyclopropanes. The reaction proceeds with high chemo and regioselectivity under mild reaction conditions typically at room temperature in a couple of hours. The reaction probably occurs via electrophilic ring-opening of cyclopropanes.
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