Journal
CHEMICAL SCIENCE
Volume 8, Issue 1, Pages 165-168Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc02668k
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- DOE [DE-FG02-13ER16370]
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LCuOTf complexes [L = cyclic (alkyl)(amino) carbenes (CAACs) or N-heterocyclic carbenes (NHCs)] selectively promote the dehydrogenative borylation of C(sp)-H bonds at room temperature. It is shown that s, p-bis(copper) acetylide and copper hydride complexes are the key catalytic species.
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