Journal
CHEMICAL SCIENCE
Volume 8, Issue 6, Pages 4660-4665Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7sc01432e
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Funding
- 973 Programs [2015CB856600]
- National Natural Science Foundation of China [21372084, 21425205, 21672067]
- Changjiang Scholars and Innovative Research Team in University (PCSIRT)
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The enantioselective construction of densely functionalized cyclopentene bearing contiguous three stereocenters has been a challenging task in organic synthesis. Herein, we present a phoshine-catalyzed highly regio-, diastereo- and enantioselective [3 + 2] cycloaddition of gamma-substituted allenoates with beta-perfluoroalkyl enones, delivering a wide range of densely functionalized perfluoroalkylated cyclopentenes with three contiguous chiral stereocenters.
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