Journal
CHEMICAL SCIENCE
Volume 8, Issue 11, Pages 7746-7750Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7sc03731g
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Funding
- Gobierno de Espana MINECO [CTQ2014-56295-R]
- FEDER [CTQ2014-56295-R]
- CERCA Programme/Generalitat de Catalunya
- MINECO
- Gobierno de Espana MINECO (Severo Ochoa Excellence Accreditation) [SEV-2013-031]
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Chiral polyimine molecular capsules with polar interiors have been prepared through template covalent dynamic self-assembly. An aryl-extended tetraaldehyde calix[4]pyrrole scaffold was condensed with suitable diamines as linkers using templates for efficient self-assembly. The capsular complexes were characterized in solution, gas phase and the solid-state. Unprecedented transfer of asymmetry was observed from a chiral diamine linker to the resulting supramolecular capsular assembly.
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