Journal
CHEMISTRY LETTERS
Volume 46, Issue 9, Pages 1288-1291Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.170509
Keywords
Coordination polymer; Gas sorption; Ru complex
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [16H02269, 26810029, 15H00983, 17H05137]
- E-IMR project
- Grants-in-Aid for Scientific Research [16H02269, 15H00983, 17H05137, 26810029] Funding Source: KAKEN
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Two zigzag-type paddlewheel Ru dimer chains with N, N, N', N'-tetramethyl-p-phenylenediamine (TMPDA) were synthesized in a solvated form (1-DCE; DCE: dichloroethane) and a non-solvated form (2), according to the Ru dimer used. Compound 1-DCE underwent crystal-to-crystal transition to its solvent-free species (1), with a characteristic structural change with respect to the contraction/expansion of solvent-accessible space. Following this transition, only 1 exhibited gate-open-type gas sorption behavior for N-2, O-2, NO, and CO2. The structures of the 1, Gas were determined by the Rietveld method based on their powder X-ray diffraction patterns under gas atmospheres.
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