Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 70, Pages 9801-9804Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05998a
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Funding
- Thailand Research Fund [RSA5880048]
- Australian Research Council
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A new air stable Fe-III spin crossover (SCO) complex has been synthesized. The compound undergoes abrupt SCO near room temperature with T-1/2 (down arrow) = 244 K and T-1/2 (up arrow) = 278 K. Structural studies of the complex in the high spin and low spin state show that the strong cooperativity and thus the wide hysteresis is driven by an unprecedented anionic conformational change.
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