Journal
DALTON TRANSACTIONS
Volume 46, Issue 27, Pages 8727-8735Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt04018g
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- Deutsche Forschungsgemeinschaft (DFG)
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Compounds consisting of [M(1,2-disila-[3n]crown-n)](2+) (M = Mg, Ca, Sr, Ba; n = 5, 6) and [Ba(1,2-disilabenzo[ 18]crown-6)](2+) cations and different anions were obtained by equimolar reaction of the hybrid disila-crown ethers 1,2-disila[15]crown-5 (1), 1,2-disila[18]crown-6 (2) and 1,2-disila-benzo[18]crown-6 (7) with alkaline earth metal salts. Even with strongly coordinating anions such as Br- or I- stable complexes could be obtained, showing the good coordination ability of these ligands. The structures of all coordination compounds were determined via single crystal X-ray diffraction (XRD). By means of DFT calculations, the complexation ability of 1,2-disila[15]crown-5 (1) towards magnesium bromide was determined to be considerably higher compared to [15]crown-5. The opposite case was observed in solution as the exchange of calcium cations between [18]crown-6 and 1,2-disila[18]crown-6 (2) was studied via dynamic proton nuclear magnetic resonance (NMR) spectroscopy.
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