Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 67, Pages 9376-9379Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc04160h
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M-MOF-74s were examined for potential applications in ethylene abatement and/or storage/delivery. Due to labile binding resulting from a Jahn-Teller distortion, Cu-MOF-74 exhibits a gradual initial uptake that, in turn, translates into the highest deliverable capacity among the MOFs examined (3.6 mmol g(-1)). In contrast, Co-MOF-74 is the most promising candidate for ethylene abatement due to the sharp uptake at low pressure.
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