Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 12, Issue 17, Pages 2207-2210Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201700922
Keywords
aggregation-induced emission (AIE); carboranes; emission; photophysical properties; tetraphenylethylene (TPE)
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Funding
- National Natural Science Foundation of China [21472086, 21531004]
- National Basic Research Program of China [2013CB922101]
- high-performance computational center of Nanjing University
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Tetraphenylethylene (TPE)-carborane hybrids are constructed, and the impact of carborane substituents on the aggregation-induced emission (AIE) characteristics of TPE-cores has been investigated. When altering the 2-R-group on the carborane unit with -H, -CH3 or phenyl group, the luminescent quantum yield of the corresponding TPE derivatives can be manipulated from 0.18 to 0.63 in the solid state. The emission color exhibits an obvious 100nm shift (from blue to yellow).
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