Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 359, Issue 17, Pages 3052-3056Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700591
Keywords
cyano migration; alkene difunctionalization; difluoroalkylation; monofluoroalkylation; photocatalysis
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Funding
- Soochow University
- National Natural Science Foundation of China [21402134]
- Natural Science Foundation of Jiangsu Province [BK20140306]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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A general protocol for the challenging cyanofluoroalkylation of unactivated alkenes is disclosed. A broad range of synthetically useful diand mono-fluorinated alkyl nitriles are readily obtained in good yields under mild reaction conditions. The efficient combination of intramolecular cyano migration and photoredox catalysis significantly expands the field of difunctionalization of olefins.
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