Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 72, Pages 9998-10001Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05221a
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Funding
- University Grants Commission (UGC), New Delhi
- Department of Science and Technology, India [EMR/2016/006500]
- Spanish Ministry of Economy and Competitiveness (Severo Ochoa)
- Spanish Ministry of Economy and Competitiveness [CTQ2015-69153-CO2-1]
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A convenient method for the synthesis of borasiloxanes from silanes and pinacolboranes using Cu-3(BTC)(2) as a heterogeneous catalyst in acetonitrile at 70 degrees C is reported. This procedure is more convenient than Ru and Pd based homogeneous catalysts because it avoids the use of noble metals, easy handling of starting materials and the catalyst can be reused.
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