Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 39, Pages 11870-11874Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201706719
Keywords
asymmetric catalysis; boron; cross coupling; nickel
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Funding
- NIH [GM-118641]
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Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C-C bond forming reactions.
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