4.7 Article

Tuning photochemical properties of phosphorus(V) porphyrin photosensitizers

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 71, Pages 9918-9921

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc06052a

Keywords

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Funding

  1. Russian Science Foundation [14-13-01373]
  2. University of Strasbourg
  3. CNRS
  4. International centre for Frontier Research in Chemistry (icFRC)
  5. Labex CSC within the Investissement d'Avenir program [ANR-10-LABX-0026 CSC, ANR-10-IDEX-0002-02]
  6. Labex CSC within the Institut Universitaire de France
  7. French Government
  8. Russian Science Foundation [17-13-00104] Funding Source: Russian Science Foundation

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Photosensitizing and emission properties of P(V) porphyrins were studied. The nature of the axial ligands, occupying the apical position on the P centre adopting an octahedral coordination geometry, strongly influences singlet oxygen generation and charge transfer and allows switching between the two processes.

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