Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 39, Pages 11822-11825Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201706134
Keywords
aromaticity; bowl-shaped molecules; C-C coupling; porphyrinoids; strained molecules
Categories
Funding
- JSPS KAKENHI [2601, JP26102003]
- Murata Science Foundation
Ask authors/readers for more resources
The synthesis of a bowl-shaped antiaromatic molecule was achieved through the deformation of a planar antiaromatic porphyrinic -conjugation system by insertion of palladium into the small cavity of a metal-free norcorrole. The bowl-to-bowl inversion dynamics of the antiaromatic Pd-coordinated norcorrole was determined by variable-temperature (HNMR)-H-1 spectroscopy. The metal-free norcorrole was prepared from acid-induced demetalation of a copper norcorrole, which was obtained from the intramolecular coupling of a bis(diiododipyrrin) copper complex with copper thiophenecarboxylate.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available