Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 70, Pages 9753-9756Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05319c
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Funding
- Polish National Science Centre within the Sonata Bis project [2016/22/E/ST5/00055]
- Polish National Science Centre within the Opus project [2014/15/B/ST5/04465]
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Two magnetic coordination polymers with mixed cyanide-azide bridging based on octacyanoniobate(IV) and octacyanomolybdate(IV) are reported: {(NH4)[(H2O)Mn-II-(mu-N-3)-Mn-II(H2O)][M-IV(CN8]center dot 3H(2)O}(n) Mn2MN3 (M = Nb or Mo). Cyanide ligands form the 3-D framework of Mn2MN3, while azide ligands connect two Mn-II centres together. Both CN- and N-3(-) are known in magnetochemistry for their marked magnetic coupling abilities which in the case of Mn2NbN3 lead to competitive antiferromagnetic interactions within the Nb-IV-CN-Mn-II and Mn-II-N-3-Mn-II structural motifs. This competition results in a peculiar magnetic behaviour consistent with a non-collinear magnetic structure.
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