Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 51, Pages 12456-12461Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201702264
Keywords
dynamic behavior; molecular star; palladium; pentanuclear complex; self-assembly
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Funding
- Science and Engineering Research Board (SERB), Department of Science and Technology, Government of India [SB/S1/IC-05/2014]
- CSIR, New Delhi, India
- JSPS, Japan
- JSPS KAKENHI [JP25104011]
- Support for Tokyotech Advanced Researchers (STAR)
- Grants-in-Aid for Scientific Research [15K21740, 25104011] Funding Source: KAKEN
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A pentanuclear coordination complex assembled from any palladium(II) component and non-chelating ligands is hitherto unreported. The pentanuclear complex [Pd-5(L1)(5)(L2)(5)](BF4)(10), 1 reported here was prepared by the spontaneous complexation of [Pd(DMSO)(4)](BF4)(2) with the non-chelating bidentate ligands 1,4-phenylenebis(methylene) diisonicotinate, L1 and 4,4-bipyridine, L2 in a one-pot method at room temperature. The planar polycyclic complex 1 with outer diameters of approximate to 3nm is termed as a molecular star owing to its resemblance with a pentagram shape. Interim paths leading to the star were also probed to decipher related dynamics of the system.
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