Journal
ACS OMEGA
Volume 2, Issue 8, Pages 4688-4692Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.7b00713
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Funding
- MOST of China [2015CB856600, 2016YFA0202900]
- National Natural Science Foundation of China [21432011, 21422209, 21421091, 21572255]
- Chinese Academy of Science [XDB20000000]
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We disclose the synthesis of a series of manganese complexes of chiral iminopyridine oxazoline ligands and their application in the first manganese-catalyzed asymmetric ketone hydrosilylations. The most sterically hindered manganese catalyst bearing two CH(Ph)(2) groups at the 2,6-ortho positions of the imino aryl ring and a tBu group on the oxazoline ring furnishes the secondary alcohols in high enantioselectivities and yields.
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