Journal
CHEMICAL PHYSICS LETTERS
Volume 686, Issue -, Pages 44-48Publisher
ELSEVIER
DOI: 10.1016/j.cplett.2017.08.007
Keywords
Transmission electron microscopy; Electron beam irradiation; Crystal growth; Ionic diffusion; Microstructure
Funding
- National key research program of China [2016YFA0300701]
- National Natural Science Foundation of China [11174336, 11374343]
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Manganese bromide has attracted enormous attention for its applications in the syntheses of organic-inorganic hybrid compounds. A complete understanding of structural and chemical stabilities of MnBr2 is important for controlling its properties. Here, we focus on the irradiation resistance of MnBr2. The chief purpose of this research is reached by in situ transmission electron microscopy. It is demonstrated that the deliquescent MnBr2 powder is prone to adsorb the vapor in air, and the hydrous MnBr2 can be decomposed under its continuous exposure to electron beam, indicated by a transmission electron microscope via the catalysis of Cu grid at room temperature. (C) 2017 Elsevier B.V. All rights reserved.
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