Journal
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Volume 72, Issue 8, Pages 617-626Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/znb-2017-0089
Keywords
imidazolium salt; ionic liquid; mercury; thione; tribromide
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A series of non-symmetric 1,3-di(alkyloxy)imidazolium salts were synthesized by stepwise alkylation of 1-hydroxyimidazole-3-oxide. The quaternary salts were subsequently functionalized by bromination in 2-position. A 2-azidoimidazolium salt and an imidazoline-2-thione were prepared exemplarily. Crystal structures of two 2-bromo-1-alkyloxy-3-methyloxyimidazolium tribromides and a mercury(II)-thione complex have been determined by X-ray diffraction.
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