Journal
CRYSTAL GROWTH & DESIGN
Volume 17, Issue 10, Pages 5552-5558Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.7b01103
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Funding
- Engineering and Physical Sciences Research Council via the Doctoral Training Partnership
- Ashland LLC
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Povidone-iodine is a widely used antiseptic and on the World Health Organization's List of Essential Medicines. We report the X-ray crystal structure of a two-monomer unit model compound showing that the structure of povidone-iodine comprises protonated pyrrolidone units linked by intermolecular hydrogen bonds along with triiodide anions. We also report an unusual example of a system exhibiting both a cocrystal and coamorphous form in a halogen bonded lactam model compound with diiodotetrafluorobenzene.
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