4.7 Article

Synthesis of Homochiral Zeolitic Tetrazolate Frameworks Based on Enantiopure Porphyrin-like Subunits

Journal

CRYSTAL GROWTH & DESIGN
Volume 17, Issue 10, Pages 5393-5397

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.7b00877

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Funding

  1. NSFC [21573236, 21425102]
  2. Haixi Institute of Chinese Academy of Sciences [CMZX-2015-001]

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The assembly of enantiopure tetrazoles with cupric ion gives rise to five homochiral zeolitic tetrazolate frameworks with rich topological nets, in which similar enantiopure porphyrin-like Cu(5-eatz)(2) subunits (SBUs) are captured in situ and play different roles.

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