Journal
ACS NANO
Volume 11, Issue 10, Pages 10088-10096Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.7b04523
Keywords
Si1-xGex nanowires; alloy; lithium-ion battery; ex situ; full-cell
Categories
Funding
- Science Foundation Ireland (SFI) [11-PI-1148]
- Irish Research Council through Government of Ireland Postgraduate Scheme
- Enterprise Ireland [CF20144014]
- Intel Ireland
- Irish Research Council through the Enterprise Partnership Scheme
- Science Foundation Ireland (SFI) [11/PI/1148] Funding Source: Science Foundation Ireland (SFI)
Ask authors/readers for more resources
Here we report the formation of high capacity Li-ion battery anodes from Si1-xGex alloy nanowire arrays that are grown directly on stainless steel current collectors, in a single-step synthesis. The direct formation of these Si1-xGex nanowires (ranging from Si0.20Ge0.80 to Si0.67Ge0.33) represents a simple and efficient processing route for the production of Li-ion battery anodes possessing the benefits of both Si (high capacity) and Ge (improved rate performance and capacity retention). The nanowires were characterized through SEM, TEM, XRD and ex situ/HRSEM/HRTEM. Electrochemical analysis was conducted on these nanowires, in half-cell configurations, with capacities of up to 1360 mAh/g (Si0.67Ge0.33) sustained after 250 cycles and in full cells, against a commercial cathode, where capacities up to 1364 inAh/g (Si0.67Ge0.33) were retained after 100 cycles.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available