Journal
CHEMISTRY LETTERS
Volume 46, Issue 10, Pages 1573-1575Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.170692
Keywords
Photochemical H-2 evolution; Artificial photosynthesis; Host-guest interaction
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [24350029, 15H03786, 2406, 24107004]
- International Institute for Carbon Neutral Energy Research (WPI-I2CNER) - World Premier International Research Center Initiative (WPI), MEXT, Japan
- Grants-in-Aid for Scientific Research [16K17879, 15H03786] Funding Source: KAKEN
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A porphyrin-based cubic cage (Cube) was reacted with a Pt(II)-based molecular H-2-evolving catalyst, PtCl2(dmbpy) (PtDmb; dmbpy: 4,4'-dimethyl-2,2'-bipyridine), to give Cubes incorporated with one or two equivalents of PtDmb, i. e., Cube(PtDmb) and Cube(PtDmb) 2, which was confirmed by ESI-TOF MS spectroscopy. A photochemical H-2-evolving system consisting of EDTA (sacrificial electron donor), [ Ru(bpy)(3)](2+) (photosensitizer), and methylviologen (electron relay) was used to demonstrate that the catalyst encapsulated can also serve as an effective H-2-evolving catalyst.
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