Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 77, Pages 10688-10691Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05225a
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Funding
- Japanese Ministry of Education, Culture, Sports, Science and Technology (MEXT)
- JSPS KAKENHI [15H03804, 15K13633]
- Grants-in-Aid for Scientific Research [15H03804] Funding Source: KAKEN
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We have developed a novel approach for the stereodivergent hydro-defluorination of gem-difluoroalkenes using copper(I) catalysts to obtain stereodefined monofluoroalkenes. Both (Z)- and (E)-terminal monofluoroalkenes were obtained by the hydrodefluorination of gem-difluoroalkenes in the presence of copper(I) catalysts and diboron or hydrosilane, respectively, with high stereoselectivity. DFT calculations were conducted to elucidate the stereoselectivity.
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