Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 42, Pages 12987-12990Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201707122
Keywords
organocatalysis; phosphine; polymers; reaction mechanisms; ring-opening polymerization
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Funding
- NSFC [21434008, 51225306]
- Department of Science and Technology of Shandong Province [2015GGX103037]
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A new superbase, the cyclic trimeric phosphazene base (CTPB), was prepared with high yield and purity. In the presence of alcohol, the CTPB serves as a highly efficient organocatalyst for ring-opening polymerization of the non-polymerizable gamma-butyrolactone to offer well-defined poly(gamma-butyrolactone) with high conversions (up to 98%) at gamma(-)60 degrees C. The produced polymers have high molecular weights (up to 22.9 kg mol(-1)) and low polydispersity distributions (1.27-1.50). NMR analysis of initiation process and the structural analysis of resulting polymers by MALDI-TOF suggest a mechanism involving an activating initiator which leads only to linear polymers with BnO/H chain ends.
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