Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 42, Pages 12862-12865Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201705557
Keywords
beta-hydride elimination; gold complexes; gold hydrides; reaction mechanisms; vinyl gold species
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Funding
- European Research Council (ERC) [307948]
- Forschungskredit of the University of Zurich
- COST Action CHAOS [CA15106]
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The first stable gold(III) formate and experimental evidence for its beta-hydride elimination are described. A catalytic dehydrogenation of formic acid together with mechanistic studies shed light on potential pathways operating in fundamental gold-catalyzed transformations.
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