Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 42, Pages 13078-13082Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201707842
Keywords
ceria; ETEM; heterogeneous catalysis; operando X-ray absorption spectroscopy; platinum
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Funding
- German Federal Ministry for Economic Affairs and Energy [BMWi: 19U15014B]
- French National Research Agency [ANR-14-CE22-0011-02]
- Agence Nationale de la Recherche (ANR) [ANR-14-CE22-0011] Funding Source: Agence Nationale de la Recherche (ANR)
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A dynamic structural behavior of Pt nanoparticles on the ceria surface under reducing/oxidizing conditions was found at moderate temperatures (< 500 degrees C) and exploited to enhance the catalytic activity of Pt/CeO2-based exhaust gas catalysts. Redispersion of platinum in an oxidizing atmosphere already occurred at 400 degrees C. A protocol with reducing pulses at 250-400 degrees C was applied in a subsequent step for controlled Pt-particle formation. Operando X-ray absorption spectroscopy unraveled the different extent of reduction and sintering of Pt particles: The choice of the reductant allowed the tuning of the reduction degree/particle size and thus the catalytic activity (CO > H-2 > C3H6). This dynamic nature of Pt on ceria at such low temperatures (250-500 degrees C) was additionally confirmed by in situ environmental transmission electron microscopy. A general concept is proposed to adjust the noble metal dispersion (size, structure), for example, during operation of an exhaust gas catalyst.
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