Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 80, Pages 10993-10996Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05987f
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Funding
- European Research Council [ERC-320441-Chirallcarbon]
- MINECO of Spain [CTQ2014-52045-R, CTQ2014-54306-P, CTQ2014-59212-P, JC IJCI-2014-19320]
- RyC [RYC-2014-16846]
- Catalan DIUE [2014-SGR-931]
- FEDER [UNGI10-4E-801]
- CAM (FOTOCARBON) [S2013/MIT-2841]
- Engineering and Physical Sciences Research Council (UK) [EP/1029451, M001962, M001970, EP/K039466]
- Ramon Areces Foundation
- European Commission [FP7-PEOPLE-2013-CIG-630978]
- ERC [ERC-2015-StG-679001]
- EC ITN MOLESCO'' [606728]
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The first chemical modification on the brand new endohedral HF@C-60 is reported. In particular, the isomerization from optically pure (2S,5S)-cis-pyrrolidino[3,4:1,2][60]fullerene 2b to (2S,5R)-transpyrrolidino[3,4:1,2][60]fullerene 2b has been studied and compared with empty C-60 (2a) and endohedral H2O@C-60 (3). The comparative study shows a kinetic order for the isomerization process of H2O@C-60 > HF@C-60 > C-60, thus confirming the effect of the incarcerated species on the zwitterionic intermediate stability.
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