Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 80, Pages 11087-11090Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05577c
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Funding
- National Natural Science Foundation of China [21274165]
- Central South University of China
- Hunan Provincial Science and Technology Plan Project, China [2016TP1007]
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A novel metallo-organic ligand [RuL2] with four uncomplexed coordination sites was created, and upon treatment with Zn2+ generated a dimetallic 3D metallosupramolecule in nearly quantitative yield. This self-assembly process gave stable intermediates, opening the pathway to the first 3D metallo-assembly possessing two Ru2+, two Fe2+, and two Zn2+ ions precisely located in the different edges. This strategy opens the door to novel designer 3D polymetallic constructs capable of diverse applications.
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