4.7 Article

Polydopamine and MnO2 core-shell composites for high-performance supercapacitors

Journal

APPLIED SURFACE SCIENCE
Volume 419, Issue -, Pages 580-585

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2017.05.080

Keywords

Polydopamine; MnO2; Core-shell nanostructure; Supercapacitor

Funding

  1. Anhui Provincial Natural Science Foundation [1408085QB45]
  2. Foundation for Innovation Team of Bioanalytical Chemistry

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Polydopamine and MnO2 core-shell composites (PDA@MnO2) for high-performance supercapacitors had been successfully synthesized by a facile and fast method. The morphology, crystalline phase and chemical composition of PDA@MnO2 composites are characterized using SEM, TEM, XRD, EDS and XPS. The performance of PDA@MnO2 composites are further investigated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy in 1 M Na2SO4 electrolyte. The PDA@MnO2 core-shell nanostructure composites exhibit a high capacitance of 193 Fg(-1) at the current density of lA ri and retained over 81.2% of its initial capacitance after 2500 cycles of charge-discharge at 2 A g(-1). The results manifest that the PDA@MnO2 composites can be potentially applied in supercapacitors. (C) 2017 Elsevier B.V. All rights reserved.

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